I worked on one about a month ago. It was private- labeled, but the same system. The exchanger (#11) closer to the exhaust from the motor / blower is a high pressure one and is the final exchanger before the system leaves the system. The one behind it (#28) is lower pressure and is used to preheat the water tank.
The copper inlet to the low pressure exchanger corroded and started leaking, so it had to be removed and inspected, repaired if possible.
Removing the exchangers was pretty straightforward, actually. Loosen and remove the plumbing and remove the (6) 1/4"-20 bolts, then slide the exchangers out.
The main problem with the job was that the bolts kept shearing off, due to corrosion from the leak. This shouldn't be the case on your system. But I highly recommend that you apply some marine grade anti seize
compound onto the bolts before screwing them back in when you re-assemble the system.
The gaskets appeared to be high temperature silicone. They weren't cut from a sheet, but were a liquid that was used to make the seal. You can probably re-use them, but just in case, it wouldn't hurt to use some liquid to make sure they fit tightly upon reinstall.
One more thing: There are rubber vibration dampeners under the "exchangers" (heater cores, actually), to keep them from being torn up by vibration as the system runs. They came loose and had to be re- positioned, then moved around some upon re-install of the exchangers. Maybe they were originally glued down. I'm not so sure. But it wouldn't hurt to glue them in place with some quick- dry contact cement first, if they're loose.