Fluorescence is simply a help in defining the scope of a contamination, it is not a qualitative analyzer insomuch as you can rely on it to differentiate between possible causes.
Old urine will generally fluoresce as a pale yellow, but can actually tend toward a dimmer bluish white for a fresher deposit. Many other bodily fluids might also exhibit coloring in these ranges, so it's difficult to wholly rely on it for differentiation. But other body fluids may a bit brighter blue/white.
Simply, you are going to suspect urine first, either by odor and/or staining, with evidence that a suspect animal was or is present to have caused it. The you use the UV light to help confirm the specific areas that are affected, and thus require treatment.
It is advisable that you use the yellow protection goggles/glasses to provide better contrasting, especially when you are using a low-wattage light or you are unable to darken the room as much as you would like. This helps eliminate blue light, accentuating the yellow more.